I have to agree with Ed that WD40 is more of a lube and not the optimal penetrant, and CRC makes pretty good stuff. Long ago and far away (ca. 1990) I spent weeks in our old barn trying to get the right side manifold off the 454 on our old Pace Arrow. Eventually I succeeded, but WD40 was little help. A foaming penetrant, incessant microvibrating the stud and block with a hammer and pin to work the penetrant in, and carefully drilling a straight hole for a bolt removal tool ultimately got the rear broken bolt out. At least twice a day I'd go down to the barn, add foam and spend time tapping, and try turning the tool. Imagine my elation when the day came that the damn thing finally cracked loose and twisted out, so I could take the warped manifold for resurfacing. Not long after, I had a Banks Powerpack with headers put on and everything was cooler running.
With WD40 I might still be making trips to the barn LOL. I had a similar issue with the clamp bolts on the exhaust pipes to that Pace after we moved here to the new house in '95. I think I used PB B'Laster brand penetrant on that, and it's my go-to now for any rusted-in bolt.
Joel