Without axle weights or, better yet, corner weights, the best guidance is to play it safe. Your tires' manufacturer prescribes 120 psi maximum [cold] per your message's text. My best guidance would be to keep your tire pressures very close to 120 psi... UNTIL you get the corner weights and then adjust your tires' pressures per a manufacturer's chart. Logically, with your tires' weight bearing capacity being 7,000 lbs (single) and 6,395 lbs (duel), compared to your coach's spec chart showing 12,000 lbs (single axle) and 19,000 lbs (duel axle), you have only 1,000 lbs and 1,645 lbs, respectively, of excess weight bearing capacity built into your tires. Without the actual corner weights, this suggests to me you need to keep your tires very close to their 120 maximum [cold] psi to play it safe - and more so on the single axle.
Our coach had 295/80R22.5 tires all around when we purchased it. I have not had the opportunity, either, to get corner weights, but I did get axle weights. Our coach's steering axle weight prompted us to go to 315/80R22.5 on the frontend. Moderate checking on both of the original tires near the tires' beads (within 3/4 in. of the rim) lead me to more promptly make the change.