After replacing the mixing valve last year I was curious to try to repair the old one. At last I found "zep Calcium Rust and Lime " remover. The valve had been completely frozen in place and two hours or so in a 50% mix of Zep and hot water freed it up completely. A bit of oil for lube and it is like new.
Warning
This product is costic so wear gloves and eye protection and don't breathe the fumes few thought they are.