George
I agree with all the above posts the first place to start in with a good servicing ( this should be an annual event )
Cleaning all the soot buildup from the combustion chamber makes a big difference on its own but as Steve said a full service involves a new nozzle, filters electrode set properly and a fuel pressure test and possibly adjustment .
The source of the white smoke is unburnt diesel fuel.
In an Aquahot the white smoke can be caused by several things I'll give you a list of things to check.
1) poorly aligned electrodes ( too far into the chamber disrupting the spray pattern of the nozzle)
2) a bad fuel nozzle spray pattern
3) a bad or leaking fuel cut off solenoid valve
(after a combustion event the fuel cut off solenoid closes to shut down the burner if it leaks it will flood the combustion chamber with raw fuel which will lay there until the next combustion event when it will be burnt off slowly causing the white smoke )
4) a sooted up combustion chamber will. Collect raw fuel rather than burning it completely and contribute to the white smoke)
5) a cracked combustion chamber allowing boiler antifreeze into the chamber will cause white smoke
( this is caused by running the boiler low on antifreeze some of the early model Aqua hots didn't have a low fluid level cut out and could suffer this failure if run low this can be tested by pressure testing the boiler with the burner and burner tube removed look for signs of antifreeze in the combustion chamber.)
6) low battery voltage will cause the motor to run slower resulting in poor air flow as well as poor fuel pressure which will cause BLACK smoke and very quickly soot up the combustion chamber .
https://youtu.be/9p5T6ixogEk?si=3E8ZsRbkDn2p1KTLhttps://youtu.be/nj_BqehNu64?si=qwYmSEgRhs-X88QFThe aqua hot will produce a small amount of white smoke on a cold startup (from a cold ambient temperature) this is normal because the boiler fluid is keeping the combustion chamber cool causing a large quench area which hinders the diesel fuel from burning completely but as the chamber comes up to temperature the white smoke should past 3 to 5 minutes .of course this is only on a dead cold startup. Once the boiler is up to temp the next burn went takes place on a warm combustion chamber and should not smoke for more than a couple of seconds .
The Aquahots tend to run rich too much fuel not enough air at elevations over 5000 ft because the air is just a little bit thinner at elevation this can be off set by opening the air inlet apature on the bottom of the burner to allow the blower to provide more air flow. ( I leave mine open all the time with no adverse effects.
Hope this helps
Eric