Dick, I turn mine on before we start our showers. By the time the DW takes hers it is warm enough for me to shower.
The Hurricane doesn't actually heat anything (regardless of the position of the master switch) until two different things occur:
First, the "operating aquastat" has to be below the turn-on temperature which, I believe is ~140F. This is, of course, likely to be the case if the system has been off.
Second, one of the thermostats or the aquastat on the hot water heater has to "call for heat." The aquastat on the H/W tank only switches on when it notices that the temperature of the water in the tank is falling (in other words when the electric heating element is failing to keep up with demand.)
So there's no particular reason to switch the system on just when you want to take a shower. It's not going to turn on until the conditions above are met. By leaving it on, it also runs while we're washing dishes which we find helpful.